You mean the lume photo?
It will not be really obvious if it is misaligned. We need to remember that the lume applied by the worker in the factory. So, slight misaligned is normal. As you know TD took this pics and zoomed it for us. So in real life, except you stare 5cm away from the watch, it looks fine.
You can ask for another watch if you are not happy. But be prepare if it's worse than your current watch. It may have a problem with bezel screw, worse alignment or even crooked DW
Dilodoli